Growth Kinetics and Optical Properties of CsPbBr3 Perovskite Nanocrystals
نویسندگان
چکیده
We synthesized CsPbBr3 perovskite nanocrystals (NCs) at different reaction temperatures and tracked their growth kinetics on the basis of optical properties estimated size. The energies absorption fluorescence (FL) peaks with increasing temperature for NCs were tuned within regions 2.429–2.570 eV 2.391–2.469 eV, respectively, depending size (9.9–12.5 nm). Stokes shifts NC decreased from 101 meV to 38 meV. full-width half-maximum FL CdSe 150 90 because improved uniformity NCs. energy spacing various was calculated Tauc plots; this information is critical determining bandgap enables be using effective mass approximation.
منابع مشابه
Thermal degradation of luminescence in inorganic perovskite CsPbBr3 nanocrystals.
The luminescence properties of inorganic perovskite CsPbBr3 nanocrystals (NCs) with emissions of 492 and 517 nm under thermal annealing treatment were studied by temperature-dependent photoluminescence (PL) spectroscopy. The CsPbBr3 NCs were annealed in vacuum at various temperatures. It was found that the NCs exhibited significant thermal degradation of PL at thermal annealing temperatures abo...
متن کاملcontrol of the optical properties of nanoparticles by laser fields
در این پایان نامه، درهمتنیدگی بین یک سیستم نقطه کوانتومی دوگانه(مولکول نقطه کوانتومی) و میدان مورد مطالعه قرار گرفته است. از آنتروپی ون نیومن به عنوان ابزاری برای بررسی درهمتنیدگی بین اتم و میدان استفاده شده و تاثیر پارامترهای مختلف، نظیر تونل زنی(که توسط تغییر ولتاژ ایجاد می شود)، شدت میدان و نسبت دو گسیل خودبخودی بر رفتار درجه درهمتنیدگی سیستم بررسی شده اشت.با تغییر هر یک از این پارامترها، در...
15 صفحه اولOptical, Photoluminescence and Thermoluminescence Properties Investigation of ZnO and Mn Doped ZnO Nanocrystals
ZnO and ZnO: Mn nanocrystals synthesized via reverse micelle method. The structural properties nanocrystals were investigated by XRD and Transmission electron microscopy (TEM). The XRD results indicate that the synthesized nanocrystals had a pure wurtzite (hexagonal phase) structure. The various optical properties of these nanocrystals such as optical band gap energy, refractive index, dielectr...
متن کاملTuning the Optical Properties of Cesium Lead Halide Perovskite Nanocrystals by Anion Exchange Reactions
We demonstrate that, via controlled anion exchange reactions using a range of different halide precursors, we can finely tune the chemical composition and the optical properties of presynthesized colloidal cesium lead halide perovskite nanocrystals (NCs), from green emitting CsPbBr3 to bright emitters in any other region of the visible spectrum, and back, by displacement of Cl(-) or I(-) ions a...
متن کاملPostsynthesis Transformation of Insulating Cs4PbBr6 Nanocrystals into Bright Perovskite CsPbBr3 through Physical and Chemical Extraction of CsBr
Perovskite-related Cs4PbBr6 nanocrystals present a "zero-dimensional" crystalline structure where adjacent [PbBr6]4- octahedra do not share any corners. We show in this work that these nanocrystals can be converted into "three-dimensional" CsPbBr3 perovskites by extraction of CsBr. This conversion drastically changes the optoelectronic properties of the nanocrystals that become highly photolumi...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Energies
سال: 2021
ISSN: ['1996-1073']
DOI: https://doi.org/10.3390/en14020275